About the Influence of Electron-hole Recombination and Partial Discharges on the Durability of Polymer Dielectrics in an Alternating Electric Field
Keywords:
polymers, electron-hole recombination, partial discharges, alternating voltage, electrical durability
Abstract
Electron-hole recombination, which occurs in polymer dielectrics in strong electric fields, and weak partial discharges in these materials are considered as possible additional factors that accelerate the aging process of polymers in an alternating electric field compared to a constant one. The effect of these factors on the rate of formation of defects (ruptures of macromolecules) is estimated. It is shown that in polymer dielectric films at a concentration of micropores of 104-105 cm-3 and intensity of partial discharges of ~ 0.01 pC, the main factor determining the decrease in electrical durability in an alternating electric field should be considered the processes of electron-hole recombination, leading to the breaking of bonds in excited macromolecules, and not erosion of the polymer as a result of partial discharges. Assuming that breakdown occurs when a critical concentration of defects that arise in a polymer dielectric due to electron-hole recombination is reached, a relation is obtained for calculating the field dependence of durability at an alternating voltage. It is shown that the calculation results are consistent with the known experimental data.
References
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12. Liufu D., Kao K.C. Capacitance Transient Spectroscopy in Metal-Insulator-Metal Systems and Its Application to the Determination of Trap Parameters in Polyimide Films. – Journal of Applied Physics, 1999, vol. 85, No. 2, pp. 1089–1094, DOI:10.1063/1.369233.
13. Пахотин В.А., Поздняков А.О., Сударь Н.Т. Летучие продукты, образующиеся при электрическом пробое пленок полиэтилентерефталата и полипропилена в высоком вакууме. – Журнал технической физики, 2022, т. 92, № 10, с. 1556–1562.
14. Alison J.M. et al. Dynamic Bipolar Charge Recombination Model for Electroluminescence in Polymer Based Insulation during Electrical Tree Initiation. – Journal Physics D: Applied Physics, 1995, vol. 28, pp. 1693–1701.
15. Lebey T., Laurent C. Charge Injection and Electroluminescence as a Prelude to Dielectric Breakdown. – Journal of Applied Physics, 1990, vol. 68, No. 1, pp. 275–282, DOI:10.1063/1.347197.
16. Le Roy S., Teyssedre G., Laurent C. Charge Transport and Dissipative Processes in Insulating Polymers: Experiments and Model. – IEEE Transactions on Dielectrics and Electrical Insulation, 2005, vol. 12, No. 4, pp. 644–654, DOI: 10.1109/TDEI.2005.1511090.
17. Mary D., Albertini M., Laurent C. Understanding Optical Emissions from Electrically Stressed Insulating Polymers: Electro-luminescence in Poly (Ethylene Terephthalate) and Poly (Ethylene 2, 6-naphthalate) Films. – Journal of Physics D: Applied Physics, 1997, vol. 30, No. 2, pp. 171–184, DOI:10.1088/0022-3727/30/2/004.
18. Абрамов В.Н. и др. Подвижность носителей заряда в полимерах. – Высокомолекулярные соединения. Серия А, 1987, т. 29, № 2, с. 260–264.
19. Семенов С.Е. и др. Механизм развития импульсного пробоя в полимерных пленках. – Физика твердого тела, 2022, т. 64, № 8, с. 948–954.
20. Сканави Г.И. Физика диэлектриков (область сильных полей). М.: Гос. изд-во физико-математической лит-ры, 1958, 907 с.
21. Боровков В.В. и др. Радиационная стойкость органических материалов. М.: Энергоатомиздат, 1986, 272 с.
#
1. Borisova M.E., Koykov S.N., Oros Ya. Elektrichestvo – in Russ. (Electricity), 1982, No. 12, pp. 53–59.
2. Berezhanskiy V.B. et al. Vysokomolekulyarnye soedineniya. Seriya A – in Russ. (High-Molecular Compounds. Series A), 1986, vol. 26, No. 10, pp. 2163–2169.
3. Mauoux C., Laurent C. Contribution of partial discharges to electrical breakdown of solid in sulating materials. – IEEE Transactions on Dielectrics and Electrical Insulation, 1995, vol. 2, No. 4, pp. 641–652, DOI: 10.1109/94.407028.
4. Kuchinskiy G.S. Chastichnye razryady v vysokovol'tnyh konstruktsiyah (Partial Discharges in High-Voltage Structures). L.: Energiya, 1979, 224 p.
5. Dissado L.A., Fothergill J.C. Electrical Degradation and Breakdown in Polymers, Ed. G.C. Stevens. London, Peter Peregrinus Ltd., 1992, 601 p.
6. Teyssedre G. et al. AC and DC Electroluminescence in Insulating Polymers and Implication for Electrical Ageing. – Journal Physics D: Applied Physics, 2001, vol. 34, No. 14, pp. 2220–2229, DOI:10.1088/0022-3727/34/14/318.
7. Danikas M.G. Small Partial Discharges and their Role in Insulation Deterioration. – IEEE Transactions on Dielectrics and Electrical Insulation, 1997, vol. 4, No. 6, pp. 863–867, DOI: 10.1109/94.654733.
8. Montanari G.C. Bringing an Insulation to Failure: The Role of Space Charge. – IEEE Transactions on Dielectrics and Electrical Insulation, 2011, vol. 18, No. 2, pp. 339–364, DOI: 10.1109/TDEI.2011. 5739438.
9. Zakrevskiy V.A., Pahotin V.A., Sudar' N.T. Fizika tverdogo tela – in Russ. (Solid State Physics), 2019, vol. 61, No. 10, pp. 1953–1959.
10. Qiao B., Laurent C., Teyssedre G. Evidence of Exciton Formation in Thin Polypropylene Films under AC and DC Fields and Relationship to Electrical Degradation. – IEEJ Transactions on Fundamentals and Materials, 2016, vol. 136, No. 2, pp. 74–80, DOI: 10.1109/ISEIM.2014.6870725.
11. Zakrevskii V.A., Pakhotin V.A., Sudar N.T. Ageing and Breakdown of Thin Insulating Polymer Films. – Journal of Applied Physics, 2014, vol. 115, No. 23, DOI:10.1063/1.4883365.
12. Liufu D., Kao K.C. Capacitance Transient Spectroscopy in Metal-Insulator-Metal Systems and Its Application to the Determination of Trap Parameters in Polyimide Films. – Journal of Applied Physics, 1999, vol. 85, No. 2, pp. 1089–1094, DOI:10.1063/1.369233.
13. Pahotin V.A., Pozdnyakov A.O., Sudar' N.T. Zhurnal tekhnicheskoy fiziki – in Russ. (Journal of Technical Physics), 2022, vol. 92, No. 10, pp. 1556–1562.
14. Alison J.M. et al. Dynamic Bipolar Charge Recombination Model for Electroluminescence in Polymer Based Insulation during Electrical Tree Initiation. – Journal Physics D: Applied Physics, 1995, vol. 28, pp. 1693–1701.
15. Lebey T., Laurent C. Charge Injection and Electroluminescence as a Prelude to Dielectric Breakdown. – Journal of Applied Physics, 1990, vol. 68, No. 1, pp. 275–282, DOI:10.1063/1.347197.
16. Le Roy S., Teyssedre G., Laurent C. Charge Transport and Dissipative Processes in Insulating Polymers: Experiments and Model. – IEEE Transactions on Dielectrics and Electrical Insulation, 2005, vol. 12, No. 4, pp. 644–654, DOI: 10.1109/TDEI.2005.1511090.
17. Mary D., Albertini M., Laurent C. Understanding Opical Emissions from Electrically Stressed Insulating Polymers: Electroluminescence in Poly (Ethylene Terephthalate) and Poly (Ethylene 2, 6-naphthalate) Films. – Journal of Physics D: Applied Physics, 1997, vol. 30, No. 2, pp. 171–184, DOI:10.1088/0022-3727/ 30/2/004.
18. Abramov V.N. et al. Vysokomolekulyarnye soedineniya. Seriya A – in Russ. (High-Molecular Compounds. Series A), 1987, vol. 29, No. 2, pp. 260–264.
19. Semenov S.Е. et al. Fizika tverdogo tela– in Russ. (Solid State Physics), 2022, vol. 64, No. 8, pp. 948–954.
20. Skanavi G.I. Fizika dielektrikov (oblast' sil'nyh poley) (Physics of Dielectrics (the Area of Strong Fields). М.: Gos. izd-vo fiziko-matematicheskoy lit-ry, 1958, 907 p.
21. Borovkov V.V. et al. Radiatsionnaya stoykost' organicheskih materialov (Radiation Resistance of Organic Materials). М.: Energoatomizdat, 1986, 272 p
2. Бережанский В.Б. и др. Электрическое старение полимерных диэлектриков при подавлении частичных разрядов. – Высокомолекулярные соединения. Серия А, 1986, т. 26, № 10, с. 2163–2169.
3. Mauoux C., Laurent C. Contribution of partial discharges to electrical breakdown of solid in sulating materials. – IEEE Transactions on Dielectrics and Electrical Insulation, 1995, vol. 2, No. 4, pp. 641–652, DOI: 10.1109/94.407028.
4. Кучинский Г.С. Частичные разряды в высоковольтных конструкциях. Л.: Энергия, 1979, 224 с.
5. Dissado L.A., Fothergill J.C. Electrical Degradation and Breakdown in Polymers, Ed. G.C. Stevens. London, Peter Peregrinus Ltd., 1992, 601 p.
6. Teyssedre G. et al. AC and DC Electroluminescence in Insulating Polymers and Implication for Electrical Ageing. – Journal Physics D: Applied Physics, 2001, vol. 34, No. 14, pp. 2220–2229, DOI:10.1088/0022-3727/34/14/318.
7. Danikas M.G. Small Partial Discharges and their Role in Insulation Deterioration. – IEEE Transactions on Dielectrics and Electrical Insulation, 1997, vol. 4, No. 6, pp. 863–867, DOI: 10.1109/ 94.654733.
8. Montanari G.C. Bringing an Insulation to Failure: The Role of Space Charge. – IEEE Transactions on Dielectrics and Electrical Insulation, 2011, vol. 18, No. 2, pp. 339–364, DOI: 10.1109/TDEI.2011. 5739438.
9. Закревский В.А., Пахотин В.А., Сударь Н.Т. Старение и разрушение (пробой) полимерных пленок в переменном электрическом поле. – Физика твердого тела, 2019, т. 61, № 10, с. 1953–1959.
10. Qiao B., Laurent C., Teyssedre G. Evidence of Exciton Formation in Thin Polypropylene Films under AC and DC Fields and Relationship to Electrical Degradation. – IEEJ Transactions on Fundamentals and Materials, 2016, vol. 136, No. 2, pp. 74–80, DOI: 10.1109/ISEIM.2014.6870725.
11. Zakrevskii V.A., Pakhotin V.A., Sudar N.T. Ageing and Breakdown of Thin Insulating Polymer Films. – Journal of Applied Physics, 2014, vol. 115, No. 23, DOI:10.1063/1.4883365.
12. Liufu D., Kao K.C. Capacitance Transient Spectroscopy in Metal-Insulator-Metal Systems and Its Application to the Determination of Trap Parameters in Polyimide Films. – Journal of Applied Physics, 1999, vol. 85, No. 2, pp. 1089–1094, DOI:10.1063/1.369233.
13. Пахотин В.А., Поздняков А.О., Сударь Н.Т. Летучие продукты, образующиеся при электрическом пробое пленок полиэтилентерефталата и полипропилена в высоком вакууме. – Журнал технической физики, 2022, т. 92, № 10, с. 1556–1562.
14. Alison J.M. et al. Dynamic Bipolar Charge Recombination Model for Electroluminescence in Polymer Based Insulation during Electrical Tree Initiation. – Journal Physics D: Applied Physics, 1995, vol. 28, pp. 1693–1701.
15. Lebey T., Laurent C. Charge Injection and Electroluminescence as a Prelude to Dielectric Breakdown. – Journal of Applied Physics, 1990, vol. 68, No. 1, pp. 275–282, DOI:10.1063/1.347197.
16. Le Roy S., Teyssedre G., Laurent C. Charge Transport and Dissipative Processes in Insulating Polymers: Experiments and Model. – IEEE Transactions on Dielectrics and Electrical Insulation, 2005, vol. 12, No. 4, pp. 644–654, DOI: 10.1109/TDEI.2005.1511090.
17. Mary D., Albertini M., Laurent C. Understanding Optical Emissions from Electrically Stressed Insulating Polymers: Electro-luminescence in Poly (Ethylene Terephthalate) and Poly (Ethylene 2, 6-naphthalate) Films. – Journal of Physics D: Applied Physics, 1997, vol. 30, No. 2, pp. 171–184, DOI:10.1088/0022-3727/30/2/004.
18. Абрамов В.Н. и др. Подвижность носителей заряда в полимерах. – Высокомолекулярные соединения. Серия А, 1987, т. 29, № 2, с. 260–264.
19. Семенов С.Е. и др. Механизм развития импульсного пробоя в полимерных пленках. – Физика твердого тела, 2022, т. 64, № 8, с. 948–954.
20. Сканави Г.И. Физика диэлектриков (область сильных полей). М.: Гос. изд-во физико-математической лит-ры, 1958, 907 с.
21. Боровков В.В. и др. Радиационная стойкость органических материалов. М.: Энергоатомиздат, 1986, 272 с.
#
1. Borisova M.E., Koykov S.N., Oros Ya. Elektrichestvo – in Russ. (Electricity), 1982, No. 12, pp. 53–59.
2. Berezhanskiy V.B. et al. Vysokomolekulyarnye soedineniya. Seriya A – in Russ. (High-Molecular Compounds. Series A), 1986, vol. 26, No. 10, pp. 2163–2169.
3. Mauoux C., Laurent C. Contribution of partial discharges to electrical breakdown of solid in sulating materials. – IEEE Transactions on Dielectrics and Electrical Insulation, 1995, vol. 2, No. 4, pp. 641–652, DOI: 10.1109/94.407028.
4. Kuchinskiy G.S. Chastichnye razryady v vysokovol'tnyh konstruktsiyah (Partial Discharges in High-Voltage Structures). L.: Energiya, 1979, 224 p.
5. Dissado L.A., Fothergill J.C. Electrical Degradation and Breakdown in Polymers, Ed. G.C. Stevens. London, Peter Peregrinus Ltd., 1992, 601 p.
6. Teyssedre G. et al. AC and DC Electroluminescence in Insulating Polymers and Implication for Electrical Ageing. – Journal Physics D: Applied Physics, 2001, vol. 34, No. 14, pp. 2220–2229, DOI:10.1088/0022-3727/34/14/318.
7. Danikas M.G. Small Partial Discharges and their Role in Insulation Deterioration. – IEEE Transactions on Dielectrics and Electrical Insulation, 1997, vol. 4, No. 6, pp. 863–867, DOI: 10.1109/94.654733.
8. Montanari G.C. Bringing an Insulation to Failure: The Role of Space Charge. – IEEE Transactions on Dielectrics and Electrical Insulation, 2011, vol. 18, No. 2, pp. 339–364, DOI: 10.1109/TDEI.2011. 5739438.
9. Zakrevskiy V.A., Pahotin V.A., Sudar' N.T. Fizika tverdogo tela – in Russ. (Solid State Physics), 2019, vol. 61, No. 10, pp. 1953–1959.
10. Qiao B., Laurent C., Teyssedre G. Evidence of Exciton Formation in Thin Polypropylene Films under AC and DC Fields and Relationship to Electrical Degradation. – IEEJ Transactions on Fundamentals and Materials, 2016, vol. 136, No. 2, pp. 74–80, DOI: 10.1109/ISEIM.2014.6870725.
11. Zakrevskii V.A., Pakhotin V.A., Sudar N.T. Ageing and Breakdown of Thin Insulating Polymer Films. – Journal of Applied Physics, 2014, vol. 115, No. 23, DOI:10.1063/1.4883365.
12. Liufu D., Kao K.C. Capacitance Transient Spectroscopy in Metal-Insulator-Metal Systems and Its Application to the Determination of Trap Parameters in Polyimide Films. – Journal of Applied Physics, 1999, vol. 85, No. 2, pp. 1089–1094, DOI:10.1063/1.369233.
13. Pahotin V.A., Pozdnyakov A.O., Sudar' N.T. Zhurnal tekhnicheskoy fiziki – in Russ. (Journal of Technical Physics), 2022, vol. 92, No. 10, pp. 1556–1562.
14. Alison J.M. et al. Dynamic Bipolar Charge Recombination Model for Electroluminescence in Polymer Based Insulation during Electrical Tree Initiation. – Journal Physics D: Applied Physics, 1995, vol. 28, pp. 1693–1701.
15. Lebey T., Laurent C. Charge Injection and Electroluminescence as a Prelude to Dielectric Breakdown. – Journal of Applied Physics, 1990, vol. 68, No. 1, pp. 275–282, DOI:10.1063/1.347197.
16. Le Roy S., Teyssedre G., Laurent C. Charge Transport and Dissipative Processes in Insulating Polymers: Experiments and Model. – IEEE Transactions on Dielectrics and Electrical Insulation, 2005, vol. 12, No. 4, pp. 644–654, DOI: 10.1109/TDEI.2005.1511090.
17. Mary D., Albertini M., Laurent C. Understanding Opical Emissions from Electrically Stressed Insulating Polymers: Electroluminescence in Poly (Ethylene Terephthalate) and Poly (Ethylene 2, 6-naphthalate) Films. – Journal of Physics D: Applied Physics, 1997, vol. 30, No. 2, pp. 171–184, DOI:10.1088/0022-3727/ 30/2/004.
18. Abramov V.N. et al. Vysokomolekulyarnye soedineniya. Seriya A – in Russ. (High-Molecular Compounds. Series A), 1987, vol. 29, No. 2, pp. 260–264.
19. Semenov S.Е. et al. Fizika tverdogo tela– in Russ. (Solid State Physics), 2022, vol. 64, No. 8, pp. 948–954.
20. Skanavi G.I. Fizika dielektrikov (oblast' sil'nyh poley) (Physics of Dielectrics (the Area of Strong Fields). М.: Gos. izd-vo fiziko-matematicheskoy lit-ry, 1958, 907 p.
21. Borovkov V.V. et al. Radiatsionnaya stoykost' organicheskih materialov (Radiation Resistance of Organic Materials). М.: Energoatomizdat, 1986, 272 p
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2023-06-29
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